MC

Current Trends in Science and Technology

an Open Access Publication ISSN: 0976-9730 | 0976-9498

Engineering and Technology

Development of formalism for temperature dependence of heat capacity of linear polymers

Dr. Minal Bafna
Department of Physics, Agrawal P.G. College, Jaipur, 302004 (Raj.), INDI.
Online First: September 03, 2017
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Abstract

In the present work authors have developed a simple phenomenological approach to deduce expressions for heat capacity at constant volume CV of linear polymers, considering both inter- and intra-molecular structural characteristic of these materials. The study reveals that correct identification and estimation of both group and skeletal vibrations is essential for the development of the formalism for CV of polymers. Further it is shown that for these materials, heat capacity at constant pressure CP can be obtained through CV   using Nernst-Lindemann equation. The computed values of CV and CP of nine polymeric samples viz. crystalline polyethylene (PE), poly (oxymethylene) (POM) and poly (tetrafluoroethylene) (PTFE); and five semi-crystalline chlorine/fluorine containing polymers, poly (vinylfluoride) (PVF), poly(vinylidenefluoride) (PVF2), poly (trifluoro ethylene) (PVF3), poly vinylidene chloride (PVC2) and polychloro-trifluoro-ethylene (PCTFE), and one  amorphous poly(vinylchloride) (PVC)  in the glassy, leathery and rubbery regions i.e over a wide temperature range (100-400K)  are in excellent agreement with the reported data (maximum deviation 5 %  for CV   and CP values). The developed formalism clearly distinguishes between crystalline, semi-crystalline and amorphous polymers and thus paves a path for better understanding of structure –property correlations in polymeric materials.

  Submitted
Sep 18, 2017
Published
Sep 3, 2017
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